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The asymmetric unit includes two crystallographically independent equivalents of the title salt, C6H7N2O2+·ClO4. The cations and anions form separate layers alternating along the c axis, which are linked by N—H...O, O—H...O and C—H...O hydrogen bonds into a two-dimensional network parallel to (100). Further C—H...O contacts connect these layers, forming a three-dimensional network, in which R44(20) rings and C22(11) infinite chains can be identified.
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