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The hydrogen-bonded two- and three-dimensional polymeric structures in the ammonium salts of 3,5-di­nitro­benzoic acid, 4-nitro­benzoic acid and 2,4-di­chloro­benzoic acid involve cation–anion N—H...O hydrogen-bonded cyclic associations. The presence or absence of the ring-stacking and ring-laddering models for ammonium carboxyl­ate structures is also tested particularly with respect to the hydrated examples.
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