metal-organic compounds
Partial oxidation of a diphenylphosphanyl group to a diphenylphosphoryl group leads to a 0.55:0.45 cocrystal. The P=O distance [1.344 (4) Å] is the shortest observed for (diphenylphosphoryl)ferrocene compounds.
research papers
Fc(PSPh2)(CH2SPSPh2), a new chiral ferrocenyl (Fc) compound, is the precursor to a new P,S-coordinating ferrocenyl ligand, [Fc(PPh2)(CH2S)]−, which reacts with Pd and Pt precursors giving dinuclear complexes displaying a butterfly geometry.