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In two organic–inorganic hybrid salts consisting of tri­methyl­sulfonium cations and polymeric {[SbCl4]}n or {[CdCl3]}n anions, the central metal atoms are coordinated by six Cl atoms, forming an anionic {[SbCl4]}n three-dimensional framework or anionic {[CdCl3]}n one-dimensional chains.
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