KNi_0.93Fe^II_0.07Fe^III(PO₄)₂: a new type of structure for a compound of composition M^IM^IIM^III(PO₄)₂

N. Yu. Strutynska, I. V. Zatovsky, V. N. Baumer, I. V. Ogorodnyk and N. S. Slobodyanik

For KNi_0.93Fe^II_0.07Fe^III(PO₄)₂, the partial substitution of Ni by Fe to give a mixed Ni/Fe site is accompanied by the redistribution of K between its original site and a newly populated position.

Keywords: crystal structure; solid solution; potassium nickel iron orthophosphate.

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KNi0.93FeII0.07FeIII(PO4)2: a new type of structure for a compound of composition MIMIIMIII(PO4)2

KNi_0.93Fe^II_0.07Fe^III(PO₄)₂: a new type of structure for a compound of composition M^IM^IIM^III(PO₄)₂