metal-organic compounds
The structural unit consists of one C2-symmetric [NbOF4]− anion, where the NbV centre is five-coordinated by four F atoms and one O atom in the first coordination shell, forming a square-pyramidal coordination geometry, and of one centrosymmetric coordinated [Cu2(obpy)2]+ cation (obpy is 2,2′-bipyridin-6-olate), in which the oxidation state of each Cu site is disordered, which is confirmed by XPS results.