organic compounds
Open access
The title compound, C9H8N2O3, was prepared by reaction of phenol, glyoxylic acid and urea in water. The imidazolidine ring adopts an almost planar conformation (r.m.s. deviation = 0.012 Å) and is twisted by 89.3 (1)° relative to the benzene ring. In the crystal, molecules are linked by N—HO and O—HO hydrogen bonds into a three-dimensional framework.
organic compounds
Open access
In the title compound, C15H10Br2, each molecule is situated on special postion mm, so the asymmetric unit contains one-quater of a molecule. The 2,7-dibromo-9H-fluorene fragment and three spirocyclopropane C atoms lie on different planes, which are perpendicular to each other. In the crystal, π–π interactions between aromatic rings [intercentroid distance = 3.699 (3) Å] pack the molecules into stacks extending in [001].
Keywords: crystal structure.