organic compounds
Open access
The title compound, C30H18ClNO, is a product of the condensation reaction of acenaphthylene-1,2-dione and 5′-chloro-1,1′:3′,1′′-terphenyl-4′-amine. The acenaphthylene fragment and two terminal phenyl rings are rotated relative to the central benzene ring by 72.2 (3), 43.2 (3) and 41.2 (3)°, respectively. This molecular conformation is supported by weak C—Hπ interactions. In the crystal, molecules form centrosymmetric dimers by the stacking interactions between two neighboring acenaphthylene fragments, with an interplanar distance of 3.365 (3) Å. The dimers are bound to each other by weak C—HN and C—Hπ interactions, forming a three-dimensional framework.
organic compounds
Open access
The title compound, C20H20Br4N2, is a product of the condensation reaction of 4,6-dibromo-2,3-dimethylaniline and butane-2,3-dione. The molecule has a center of symmetry at the mid-point of the central C-C bond. The dihedral angle between the benzene ring and the 1,4-diazabutadiene plane is 78.3 (2)°. Niether hydrogen bonding nor aromatic stacking is observed in the crystal structure.
organic compounds
Open access
In the title compound, C19H15N3O2·H2O, the oxadiazole ring and the quinoline unit are almost coplanar, making a dihedral angle of 7.66 (8)°. The dihedral angle between the benzene ring and the quinoline system is 25.95 (8)° while that between the benzene and the oxadiazole rings is 18.88 (9)°. The water molecule is hydrogen bonded to an oxadiazole N atom and to the quinoline N atom. In the crystal, these units are linked via C—HO hydrogen bonds, forming two-dimensional networks lying parallel to the ab plane.