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In the title compound, C16H16ClNO2S, the benzene and thio­phene rings make a dihedral angle of 72.60 (4)°. In the crystal, weak C—H...O inter­actions are observed.

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In the title mol­ecular salt, (C4H10NO)2[CoCl4], the morpholinium cations adopt chair conformations and the tetra­chloridocobaltate(II) anion is significantly distorted from regular tetra­hedral geometry [Cl—Co—Cl = 102.183 (19)–117.59 (2)°]. The Co—Cl bond lengths for the chloride ions not accepting hydrogen bonds are significantly shorter than those for the chloride ions accepting such bonds. In the crystal, the components are linked by N—H...O and N—H...Cl and bifurcated N—H...(O,Cl) hydrogen bonds to generate (100) sheets.
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