organic compounds
Open access
The title compound congestiflorone, C28H32O4, which was isolated from the stem bark of Mesua congestiflora, consists of a benzophenone skeleton with two attached pyran rings to which a cyclohexane ring and a C6 side chain are bonded. The benzene ring is significantly distorted from planarity (r.m.s. deviation = 0.0007 Å) due to the constraints imposed by junctions with the two pyran rings. The cyclohexane ring is in a chair conformation, one pyran ring is in a boat conformation, while the other is a distorted chair. The phenyl and benzene rings make a dihedral angle of 55.85 (9)°. An intramolecular O—HO hydrogen bond is observed. In the crystal, molecules are linked via C—HO interactions.
organic compounds
Open access
The title compound, C17H16N2O3, has an E conformation about the azobenzene (–N=N–) linkage. The benzene rings are twisted slightly with respect to each other [6.79 (9)°], while the dihedral angle between the plane through the carboxy group and the attached benzene ring is 3.2 (2)°. In the crystal, molecules are oriented with the carboxy groups head-to-head, forming O—HO hydrogen-bonded inversion dimers. These dimers are connected by C—HO hydrogen-bonds into layers lying parallel to the (013) plane.
organic compounds
Open access
In the title compound, C26H24N2O2, the benzimidazole ring system is almost planar [maximum displacement = 0.025 (1) Å] and makes dihedral angles of 80.48 (5) and 41.57 (5)° with the benzene rings, which are inclined to one another by 65.33 (6)°. In the crystal, molecules are linked via C—Hπ and weak π–π interactions [centroid–centroid distance = 3.8070 (7) Å and interplanar distance = 3.6160 (5) Å].