organic compounds
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The cyclohexene ring in the title compound, C15H18INO2, adopts a sofa conformation. The dihedral angle between the cyclohexene (through all ring atoms) and benzene rings is 63.3 (1)°. The molecular conformation features an N—HI short contact and the crystal packing features C—HO hydrogen bonds.
organic compounds
Open access
In the title compound, C25H18N2O3S, the indole moiety is planar and makes a dihedral angle of 89.95 (09)° with the phenyl ring of the sulfonyl substituent. The molecular conformation features a weak C—HN short contact and the crystal packing reveals a weak C—HO hydrogen bond.
organic compounds
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In the title compound, C25H23N, the indole unit makes a dihedral angles of 79.03 (5) and 61.82 (4)° with the benzene rings. No classical hydrogen bonds are found in the crystal structure.
organic compounds
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In the title compound, C24H22N2O3, the indoline and pyrrole-fused naphthoquinone units are both essentially planar [r.m.s. deviations = 0.042 (3) and 0.133 (3) Å, respectively]. The pyrrole ring adopts a C-envelope conformation. The dihedral angle between the mean planes of the two five-membered rings is 89.94 (9)°. The O atoms deviate from the mean planes of the pyrrolidine and naphthalene rings by 0.0311 (2), 0.2570 (2) and 0.1669 (2) Å. In the crystal, C—HO interactions generate dimers with R22(16) and R22(18) graph-set motifs. The carbonyl O atom is involved in bifurcated hydrogen bonding. C—Hπ interactions also occur.