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The title compound, C26H26S4, shows a dihedral angle of 76.64 (15)° between the central and peripheral benzene rings. An inversion center is located at the centroid of the thio­benzoyl ring. In the crystal, weak C—H...S inter­actions form C(5) chains along [001]. There are no classical hydrogen bonds.

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In the title isobenzo­furan­one derivative, C20H15NO2, the planar fused-ring system (r.m.s. deviation for the 10 fitted atoms = 0.031 Å) forms dihedral angles of 63.58 (6) and 63.17 (8)° with the N-bound phenyl rings; the dihedral angle between the planes of these phenyl rings is 85.92 (7)°. In the crystal, mol­ecules are linked by weak C—H...O inter­actions, involving both O atoms, forming helical supra­molecular chains along [001].

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In the title picryl-substituted ester, C13H6BrN3O8, the mean plane of the central ester C–O–C(=O)–C fragment (r.m.s. deviation= 0.0186 Å) is rotated by 84.73 (7)° and 19.92 (12)° to the picryl and phenyl rings, respectively. In the crystal, the mol­ecules are linked by C—H...O inter­actions, forming centrosymmetric dimers enclosing R22(10) and R22(22) ring motifs along [001] and further helical chains of dimers enclosing R22(10) ring motifs along [010].
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