organic compounds
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In the title hydrated salt, C16H13ClN3+·Cl−·2H2O, a small twist is evident in the cation so that the chlorobenzene ring is not coplanar with the central hydrazinyl group [the N—C—C—C torsion angle = −4.8 (12)°]. The conformation about the imine N=C bond [1.284 (10) Å] is E. The components of the structure are connected into a three-dimensional architecture via O—HO, O—HCl and N—HCl hydrogen bonds. One water H atom is disposed over two sites of equal occupancy.