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The title compound, C12H10N2O2·H2O, crystallizes as a zwitterion in which the pyridine N atom is protonated and the carb­oxy –OH group is deprotonated. The benzene and pyridinium rings are inclined with a dihedral angle of 6.63 (5)° between them. In the crystal, inter­molecular O—H...O and N—H...O hydrogen-bonding inter­actions link adjacent mol­ecules into a two-dimensional double layered supra­molecular network.
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