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In the title complex, [Co(C18H18N2O4)(C2H3O2)(H2O)]·2CH3OH, the CoIII atom is hexa­coordinated by water and acetate groups in the axial positions and by the tetra­dentate Schiff base occupying equatorial positions. These axial bonds are longer than the equatorial bonds to the tetra­dentate Schiff base. Two mol­ecules form a dimer through strong hydrogen bonds from the coordinated water of one mol­ecule to the meth­oxy O atoms of an adjoining mol­ecule. There is extensive intra- and inter­molecular O—H...O hydrogen bonding between the coordinated water and acetate ligands and the methanol solvent mol­ecules. In addition, there are weak inter­molecular C—H...O inter­actions, which link the mol­ecules into a three-dimensional array.
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