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In the title compound, [Cu(C2H3O2)2(C12H12N2)2]·H2O, the CuII atom exhibits a distorted octa­hedral coordination geometry, defined by two N atoms from one 4,4′-dimethyl-2,2′-bipyridine ligand and four O atoms from two acetate ligands. In the crystal, O—H...O hydrogen bonds are observed between the coordinated carboxyl­ate O atoms and the solvent water mol­ecule.
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