1,3-Bis{[(4-methyl­phen­yl)sulfon­yl]­oxy}propan-2-yl 4-methyl­benzene­sulfonate

In the title sulfonate derivative, C₂₄H₂₆O₉S₃, all atoms apart from those of one of the 4-methyl­benzene­sulfonate residues lie approximately in a disc; the dihedral angles between the approximately orthogonal benzene ring and those in the plane are 74.53 (9) and 67.79 (11)°. In the crystal, mol­ecules are consolidated into the three-dimensional architecture by C—H...O inter­actions. One of the 4-methyl­benzene­sulfonate residues is disordered over two almost parallel positions; the major component refined to a site-occupancy factor of 0.918 (2).

Methyl 2-[(3,5-di-tert-butyl-4-hy­droxy­benz­yl)sulfan­yl]pyridine-3-carboxyl­ate n-hexane hemisolvate

The title solvated ester, C₂₂H₂₉NO₃S·0.5C₆H₁₄, crystallizes with two independent mol­ecules along with a hexane mol­ecule in the asymmetric unit. The two aromatic rings are separated by an –CH₂–S– linkage; the rings are aligned at 83.27 (4)° in one mol­ecule and 47.66 (7)° in the other. The hy­droxy group of one mol­ecule forms an O—H...O hydrogen bond to the other mol­ecule.