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The title centrosymmetric compound, [Cu2(C8H7O3)4(C2H3N)2], is a carboxyl­ate-bridged dinuclear CuII complex with four phenoxy­acetate and two acetonitrile mol­ecules as ligands. Each of the four phenoxy­acetate anions straddles the pair of Cu atoms, the Cu—Cu distance being 2.6618 (10) Å. A weak C—H...π inter­action connects the dinuclear CuII units into a one-dimensional chain.
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