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The mol­ecules of the title compound, C13H14O4, the condensation product of vanillin and acetyl­acetone, are hydrogen bonded into a linear chain arising from interaction between the hydroxy group of one mol­ecule and the acetyl group of an adjacent mol­ecule.

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The mol­ecules of the title compound, C16H12O4, are linked by hydrogen bonds involving the two hydr­oxy and carbon­yl O atoms, forming a three-dimensional network.
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