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In the title compound, C21H44S2, the molecular skeleton including both terminal S atoms has an all-trans conformation. The mol­ecules form layers with a thickness of c/2 and the long axis of the mol­ecule is inclined to the ab plane in the crystal structure. This molecular arrangement is similar to that of the smectic C structure of liquid crystals.

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In the title compound, C23H48S2, the mol­ecular skeleton, including both terminal S atoms, has an all-trans conformation. The mol­ecules form layers in the crystal. The long axis of the mol­ecule is inclined to the layer plane, similar to the smectic C phase of liquid crystals.
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