Bis­[2-mercapto­pyridine N-oxide(1–)-κ²N,O]­platinum(II)

The title complex, [Pt(C₅H₄NOS)₂], shows a trans-S₂O₂ square-planar coordin­ation geometry for the Pt^II centre. The mol­ecule self-assembles into a two-dimensional layer through weak intermolecular C—H...O/S/N interactions.

Bis(2-oxopyridinato N-oxide-κ²O,O′)copper(II)

The title complex, [Cu(C₅H₄NO₂)₂], displays a trans-O₂(N-oxide)O₂ square-planar coordination geometry for the Cu^II centre. In the crystal structure, the mol­ecules assemble into a three-dimensional structure by way of intermolecular π–π interactions and weak intermolecular C—H...O interactions.