organic compounds
In the crystal structure of the title compound, C13H11NO5S, the dihedral angle between the mean planes of the 4-tolyl and 4-nitrophenyl rings is 82.52 (4)°. There are weak C—HO interactions, which generate rings of graph-set motifs S(5), S(6), (5), (6) and (9). The supramolecular aggregation is completed by the presence of C—Hπ and van der Waals interactions.
organic compounds
In the crystal structure of the title compound, C14H14O3S, the dihedral angle between the planes of the two benzene rings is 45.51 (5)°. There are weak C—HO hydrogen bonds which generate rings of graph-set motifs S(5), S(6) and R21(6). The supramolecular aggregation is completed by the presence of C—Hπ and π–π interactions.
organic compounds
In the crystal structure of the title compound, C14H14O3S, the dihedral angle between the mean planes of the two rings is 51.97 (8)°. There are weak C—HO hydrogen bonds which generate rings of graph-set motifs S(5), S(6), R12(4) and R21(9). The supramolecular aggregation is completed by the presence of C—Hπ interactions.
organic compounds
In the crystal structure of the title compound, C17H14O3S, the dihedral angle between the mean planes of the 4-tolyl and 1-naphthyl rings is 45.05 (4)°. The supramolecular aggregation is completed by the presence of intermolecular C—HO and C—Hπ interactions.
metal-organic compounds
The title compound, C28H26N2Te2, prepared by reduction of (3,5-dimethylphenyl)(2-nitrophenyl)tellurium(II), is the first structurally characterized example of an azo group bridging two TeII centers. The compound is centrosymmetric and the Te—N distance [2.6916 (19) Å] is longer than in non-bridging azo compounds.
metal-organic compounds
The title compound, mer-[RuCl3(C10H8N2)(C4H8OS)]·CH2Cl2 or mer-[RuCl3(bpy)(TMSO)]·CH2Cl2, has the TMSO ligand coordinated through the S atom, with an Ru-S distance of 2.3042 (7) Å. The Ru-Cl distances are in the range 2.3324 (7)-2.3649 (8) Å, with the longest trans to N. The solvent molecule is ordered.
organic compounds
In the crystal structure of the title compound, C13H11BrO3S, the dihedral angle between the mean planes of the 4-tolyl and 4-bromophenyl rings is 67.3 (2)°. There are weak C—HO hydrogen bonds which generate rings of graph-set motifs S(5), S(6), R12(4), R21(6) and R22(8). The supramolecular aggregation is completed by the presence of C—Hπ interactions. An R22(7) motif formed by the combination of a C—HO and a C—Hπ interaction is a notable feature in the title compound.