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The MnIII ion in the title compound shows a slightly distorted octahedral coordination geometry with two O and four N atoms of the pyrrolyl derivative ligand. In the crystal, intermolecular N—HO hydrogen bonds between the pyrrole group of the ligand and the uncoordinated nitrate ion give a chain structure along [10].
research communications
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The FeIII ion in the title compound shows a slightly distorted FeCl2N2O2 octahedral coordination geometry. In the crystal, two complex molecules are linked by duplex O—HO hydrogen bonds. Additional hydrogen-bonding interactions lead to the formation of undulating sheets parallel to (010).