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In the title compound, [SbBr(C10H7)2], the SbIII atom has a distorted trigonal–pyramidal coordination geometry and the planes of the two naphthalene ring systems make a dihedral angle of 80.26 (18)°. An intramolecular C—HBr hydrogen bond forms an S(5) ring motif. In the crystal, weak C—HBr interactions link the molecules into helical chains along the b-axis direction.