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The title compound possesses crystallographically imposed twofold symmetry with two C atoms lying on the rotation axis and has a non-coplanarly accumulated aromatic-rings structure. In the crystal, C—H...O=C hydrogen bonds between the benzene rings and the carbonyl groups and C—H...O=N hydrogen bonds between the benzene rings and the nitro groups are observed; these C—H...O hydrogen bonds link the mol­ecules, forming a three-dimensional structure.

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In 1,8-dibenzoyl-2,7-di­phen­oxy­naphthalene, the planes of the benzene rings of the four naphthalene substituents are almost perpendicular to that of the naphthalene core.

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The asymmetric unit of the compound contains two independent conformers. Each conformer is stacked along the a axis to form columns through van der Waals inter­actions only.
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