metal-organic compounds
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In the title compound, [FeBr(C9H9NO2S)(C30H30N2P2)][B(C6H5)4], the FeII ion is in a distorted octahedral CBrN2P2 coordination geometry with a P—Fe—P angle of 109.95 (3)°. The relative orientation of the p-toluenesulfonylmethyl isocyanide ligand is defined by the C—S—C—N torsion angle of 67.1 (2)°. In the crystal, pairs of weak C—HO hydrogen bonds connect the cations into inversion dimers, forming R22(8) rings.