Bis[2-(1,3-benzo­thia­zol-2-yl)phenyl-κ²C¹,N][1,3-bis­(4-bromo­phen­yl)propane-1,3-dionato-κ²O,O′]iridium(III)

The title complex, [Ir(C₁₅H₉Br₂O₂)(C₁₃H₈NS)₂], lies about a crystallographic twofold rotation axis passing through the Ir^III atom and the central C atom of the bis­(bromo­phen­yl)propane-1,3-dionate ligand. The Ir^III atom adopts a distorted octa­hedral geometry coordinated by two N atoms in the axial positions, and two C and two O atoms in the equatorial plane. The dihedral angle between the two thia­zole ring systems in the complex is 77.45 (10)°.

1-Benzoyl-4-thio­biuret

In the title compound (systematic name: {[(phenyl­formamido)­carbon­yl]amino}­methane­thio­amide), C₉H₉N₃O₂S, both benzoyl and terminal thio­urea fragments adopt transoid conformations with respect to the central carbonyl O atom. The benzoyl and thio­biuret groups are almost coplanar, making a dihedral angle of 4.40 (8)°. The mol­ecular structure is stabilized by two intra­molecular N—H...O hydrogen bonds. In the crystal, N—H...O and N—H...S hydrogen bonds link the mol­ecules into a tape running along [101].