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The title compound, C19H20N2O·C2H5OH, is an ethanol solvate of an indol alkaloid which was extracted from the plant Vinca erecta. The fused piperidine ring adopts an approximate boat conformation and the pyrrolidine ring an envelope conformation with one of the methyl­ene C atoms at the flap. An intra­molecular N—H...O hydrogen bond forms an S6 ring motif. In the crystal, norfulorocurarine and ethanol mol­ecules are linked into a chain along the c-axis direction through N—H...O and O—H...N hydrogen bonds.

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In the title salt, C2H10N22+·2C14H10NO3, the ethyl­ene­diaminium dication lies on an inversion centre. In the anion, the benzene rings make a dihedral angle of 33.87 (9)° and intramolecular N—H...O and C—H...O hydrogen bonds occur. All the amino H atoms are involved in N—H...O hydrogen bonds. These hydrogen bonds link the ionic units into a three-dimensional network. In addition, the crystal structure also features weak C—H...O inter­actions.
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