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In the title compound, {[Zn(C8H4O4)(C6H6N2O)2]·C6H6N2O}n, the ZnII ion exhibits a tetra­hedral coordination environment defined by two benzene-1,4-dicarboxylate dianions and two 4-pyridinealdoxime ligands. The dianions bridge the ZnII ions, giving a zigzag chain along the b axis. Adjacent chains are connected by O—H...O hydrogen bonds, forming a cavity in which an uncoordinating 4-pyridine­aldoxime mol­ecule is located; this mol­ecule is linked by O—H...O and O—H...N hydrogen bonds to the zigzag chain.
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