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In the cation of the title salt, C23H27N2O4+·C2HO4·2H2O, both fused pyrrolidine rings exhibit twisted conformations, while the piperidine rings adopt screw-boat and boat conformations. In the crystal, the three components are linked via O—H...O and N—H...O inter­actions, forming a tape along the b axis. The tapes are further linked by weak C—H...O hydrogen bonds. forming a three-dimensional network.

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In the cation of the title compound, C14H13BrN+·C7H7O3S, the dihedral angle between the benzene and pyridine rings is 8.34 (11)°. The Br atom is disordered over two positions with site occupancies of 0.74 (2) and 0.26 (2). The mol­ecular structure is stabilized by a weak intra­molecular C—H...O inter­actions. The crystal structure exhibits weak C—H...O and π–π [centroid–centroid distance = 3.7466 (17) Å] inter­actions, forming a three dimensional network.

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In the title mol­ecular salt, C18H22NO+·C7H7O3S, the dihedral angle between the aromatic rings in the cation is 10.00 (9)°; its alkyl side chain adopts an extended conformation. In the crystal, weak C—H...O and π–π [centroid–centroid distance = 3.7658 (17) Å] inter­actions link the components, generating a three-dimensional network.

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The asymmetric unit of the title salt, C3H7N6+·C6H7O4·C3H4O2·H2O, contains a 2,4,6-tri­amino-1,3,5-triazin-1-ium cation, a 3-(prop-2-eno­yloxy)propano­ate anion and acrylic acid and water solvent mol­ecules in a 1:1:1:1 ratio and with each species in a general position. In the crystal, the components are linked into a supra­molecular layer in the bc plane via a combination of O—H...O, N—H...N and N—H...O hydrogen bonding. The crystal studied was a non-merohedral twin, the minor component contribution being approximately 26%.

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In the title salt, C8H12N+·C7H5O3, the cation is disordered over two orientations with site occupancies of 0.565 (7) and 0.435 (7). In the anion, the carboxyl­ate group makes the dihedral angle of 4.19 (18)° with the benzene ring. In the crystal, the ions are connected by N—H...O and O—H...O hydrogen bonds, forming a three-dimensional network.
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