metal-organic compounds
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In the title compound, [Fe(C5H5)(C16H15O3)], the cyclopentadienyl rings are in an eclipsed conformation and the benzene ring makes dihedral angles of 10.84 (9) and 12.35 (9)°, respectively, with the substituted and unsubstituted cyclopentadienyl rings. In the crystal, molecules form inversion dimers through pairs of O—HO hydrogen bonds. Weak C—HO hydrogen bonds are observed between the dimers.
organic compounds
Open access
In the title compound, C28H24ClNO3, the dihedral angles between the central benzene ring and the indole ring system and the chlorobenzene ring are 70.81 (5) and 78.62 (5)°, respectively. The molecular structure is stabilized by a weak intramolecular C—HO interaction. In the crystal, pairs of C—HO hydrogen bonds link the molecules into inversion dimers with an R22(14) motif.
metal-organic compounds
Open access
In the title compound, [Fe(C5H5)(C14H10NO3)], the cyclopentadienyl rings are in an eclipsed conformation and the pyran ring adopts a half-chair conformation. The mean plane of the pyran ring makes dihedral angles of 79.33 (1) and 80.73 (1)°, respectively, with the substituted and unsubstituted cyclopentadienyl rings. In the crystal, pairs of C—HO hydrogen bonds link the molecules into inversion dimers with R22(16) motifs.
organic compounds
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The title compound, C19H17NO5, comprising two stereogenic C atoms of the same configuration, crystallizes in a centrosymmetric space group as a racemate. The pyran ring adopts a half-chair conformation, while the isoxazole ring adopts an envelope conformation with the C atom bonded to the methoxyphenyl group as the flap. The dihedral angle between the mean plane of the pyran ring and the adjacent benzene ring is 5.86 (5)°. In the crystal, molecules are linked by a weak C—HO hydrogen bond, forming a chain along the a axis.
organic compounds
Open access
The title compound, C17H11ClN2O2, which contains two stereogenic C atoms, crystallizes in a centrosymmetric space group as a racemate. The pyran ring and the isoxazole ring adopt sofa and twisted conformations, respectively. The dihedral angle between the benzene ring and the mean plane through the near coplanar atoms of the pyran ring is 4.17 (5)°. The molecular conformation features a weak C—HO contact. In the crystal, C—HO hydrogen bonds link the molecules, forming chains along the a-axis direction.