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In the title salt, C23H21NOP+·Br, the dihedral angles between the phenyl rings are 70.41 (18), 73.6 (2) and 80.85 (19)°. In the crystal, neighboring mol­ecules are linked through an N—H...Br hydrogen bond and four weak C—H...Br contacts, forming a three-dimensional network.

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In the title compound, C12H15NO4, the dihedral angle between the acetamide group and the ring is 29.6 (2)(su?)°. In the crystal mol­ecules are linked through N—H...O and O—H...O hydrogen bonds, thereby forming corrugated sheets propagating in the ac plane. These sheets are composed of R44(28) graph-set motifs.
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