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The base mol­ecule of the title co-crystal, C7H10N2O2S·C7H6O3, is essentially planar, with a maximum deviation of 0.0806 (14) Å for all non-H atoms. The acid mol­ecule is also nearly planar, with a dihedral angle of 8.12 (14)° between the benzene ring and the carb­oxy group. In the crystal, the acid mol­ecules form an inversion dimer through a pair of O—H...O hydrogen bonds with an R22(8) ring motif. The pyrimidine mol­ecules are linked on both sides of the dimer into a heterotetra­mer via O—H...N and C—H...O hydrogen bonds with R22(8) ring motifs. The heterotetra­mers are further linked by weak C—H...O hydrogen bonds, forming a tape structure along [1-10].
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