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In the title compound, C10H11N5O, the triazine ring forms a dihedral angle of 10.37 (4)° with the benzene ring. In the crystal, adjacent mol­ecules are linked by a pair of N—H...N hydrogen bonds, forming an inversion dimer with an R22(8) ring motif. The dimers are further connected via N—H...O and N—H...N hydrogen bonds, resulting in a three-dimensional network.

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The asymmetric unit of the title compound, 2C10H11N5O·C6H10O4, consists of a 2,4-diamino-6-(4-meth­oxy­phen­yl)-1,3,5-triazine mol­ecule and one-half mol­ecule of adipic acid which lies about an inversion center. The triazine ring makes a dihedral angle of 12.89 (4)° with the adjacent benzene ring. In the crystal, the components are linked by N—H...O and O—H...N hydrogen bonds, thus generating a centrosymmetric 2 + 1 unit of triazine and adipic acid mol­ecules with R22(8) motifs. The triazine mol­ecules are connected to each other by N—H...N hydrogen bonds, forming an R22(8) motif and a supra­molecular ribbon along the c axis. The 2 + 1 units and the supra­molecular ribbons are further inter­linked by weak N—H...O, C—H...O and C—H...π inter­actions, resulting in a three-dimensional network.
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