organic compounds
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The asymmetric unit of the title compound, C8H8ClNO3S, consists of two crystallographically independent molecules (A and B). The dihedral angles between the benzene ring and amide C—C(=O)—NH– plane are 87.6 (3) (molecule A) and 86.0 (3)° (molecule B). In the crystal, the independent molecules are alternately linked by N—HO hydrogen bonds into an infinite chain along the b axis. Short intermolecular ClCl contacts [3.2882 (5) and 3.2812 (5) Å] are also observed.