organic compounds
Open access
In the title compound, C17H23N3O6, the two methoxycarbonyl C—O—C=O planes are inclined at dihedral angles of 5.3 (4) and 83.9 (4)° with respect to the central pyridine ring. An intramolecular N—HO hydrogen bond generates an S(5) ring motif. In the crystal, molecules are linked into a chain along the c axis via C—HO hydrogen bonds.
organic compounds
Open access
In the title compound, C23H20FNO4, the fluoro-substituted benzene ring is approximately perpendicular to the mean plane of the 4H-benzo[h]chromene ring system [maximum deviation = 0.264 (1) Å], with a dihedral angle of 83.79 (6)°. The pyran ring adopts a flattened boat conformation. The methoxy group is slightly twisted from the attached benzene ring of the 4H-benzo[h]chromene moiety [C—O—C—C = −2.1 (2)°]. An intramolecular N—HO hydrogen bond generates an S(6) ring motif. In the crystal, molecules are linked by N—HO and N—HF hydrogen bonds into a layer parallel to the bc plane. The crystal packing also features C—Hπ interactions.
organic compounds
Open access
In the title compound, C15H19N3O6, the amide planes are inclined at dihedral angles of 0.8 (6) and 12.1 (3)° with respect to the central pyridine ring. The mean planes of the corresponding methyl acetate groups form dihedral angles of 41.76 (13) and 86.48 (15)°, respectively with the mean plane of pyridine ring. A pair of weak intramolecular N—HN hydrogen bonds generate an S(5)S(5) ring motif in the molecule. In the crystal, molecules are linked by N—HO hydrogen bonds into [001] chains. The chains are cross-linked by C—HO hydrogen bonds into layers lying parallel to bc plane. The crystal packing also features a C—Hπ interaction.
organic compounds
Open access
In the title molecule, C21H15FN2O2, the dihedral angle between the fluoro-substituted benzene ring and the mean plane of the 4H-benzo[h]chromene ring system [maximum deviation = 0.109 (2) Å] is 83.35 (7)°. The pyran ring adopts a slight sofa conformation with the tertiary C(H) atom forming the flap. The methoxy group is slightly twisted from the attached benzene ring of the 4H-benzo[h]chromene moiety [C—O—C—C = −4.3 (3)°]. In the crystal, molecules are linked by intermolecular N—HN hydrogen bonds into infinite wave-like chains along the b axis. The crystal packing is further stabilized by π–π interactions [centroid–centroid distance = 3.7713 (9) Å].