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In the title compound, [Na(C6H3Cl2O3S)(H2O)]n, the NaI ion is penta­coordinated by three dichloro­benzene­sulfonate anions and two water mol­ecules, forming a distorted trigonal-bipyramidal geometry. The NaI ions are bridged by the sulfonate groups and the water mol­ecules, leading to a polymeric layer structure parallel to the bc plane in which O—H...O hydrogen bonds are observed.
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