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The asymmetric unit of the title Pb-based coordination polymer, [Pb2(C24H16N2O8)(H2O)2]n, consists of one PbII cation, half of a 4,4′-(1,4-phenyl­ene)bis­(2,6-dimethyl­pyridine-3,5-di­carb­oxyl­ate (L4−) ligand and one coordinating water mol­ecule. The centers of the benzene ring of the ligand and the four-membered Pb/O/Pb/O ring are located on centers of inversion. The PbII ion is coordinated in form of a distorted polyhedron by seven O atoms from four separate L4− ligands and by one water O atom. The PbO7 polyhedra share O atoms, forming infinite zigzag [PbO4(H2O)]n chains along [100] that are bridged by L4− ligands, forming a two-dimensional coordination network parallel to (001). O—H...O hydrogen bonds involving the water mol­ecule are observed.
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