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metal-organic compounds
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The title compound, [Ru(C7F5O2)2(C10H14)(C21H24N2)]·2CH2Cl2, is formed as an orange crystalline powder by the reaction of RuCl2(p-cymene)(IMes) and AgOCOC6F5 in anhydrous tetrahydrofuran (IMes = 1,3-dimesityl-2,3-dihydro-1H-imidazol-2-ylidene). The asymetric unit consists of two independent [Ru(C6F5COO)2(η6-p-cymene)(IMes)] complexes and four dichloromethane solvent molecules. In each complex molecule, the Ru atom presents a pseudo-octahedral environment with the p-cymene ligand occupying three facial coordination sites, while the remaining coordination positions are occupied by the O atoms of the pentafluorobenzoate ligands and by the imidazolylidene ligand.
organic compoundsOpen access
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In the title compound, C10H17IO5, the six-membered tetrahydropyran ring and the five-membered 1,3-dioxolane ring adopt sofa and envelope conformations, respectively. In the crystal, O—H
O and C—HO hydrogen bonds link the molecules into layers nearly parallel to the bc plane.
O and C—HO hydrogen bonds link the molecules into layers nearly parallel to the bc plane.organic compoundsOpen access
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In the title compound, C14H14INO4, the dihydropyridine ring adopts a twist conformation. In the crystal, pairs of N—HO and C—HO hydrogen bonds link the molecules into inversion R22(10) and R22(18) dimers, forming infinite double chains running along the c axis.
O and C—HO hydrogen bonds link the molecules into inversion R22(10) and R22(18) dimers, forming infinite double chains running along the c axis.
