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The title complex, {(C16H12FN2)[PbI3]}n, consists of 1-[(2-fluoro­benzyl­idene)amino]­quinolinium cations and a polymeric PbI3 anion formed by face-sharing PbI6 octa­hedra. These octa­hedra form straight and regular infinite chains along the b axis. In the asymmetric unit, one cation and one anionic [PbI3] fragment are observed in general positions. Polymeric chains are produced by the glide plane perpendicular to the a axis.
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