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metal-organic compounds
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In the title complex, [Ni(NCS)2(C6H6N2O)2(H2O)2], the NiII ion is located on an inversion center and is coordinated in a distorted octahedral environment by two N atoms from two nicotinamide ligands and two water molecules in the equatorial plane, and two N atoms from two thiocyanate anions in the axial positions, all acting as monodentate ligands. In the crystal, weak N—H
S hydrogen bonds between the amino groups and the thiocyanate anions form an R42(8) motif. The complex molecules are linked by O—HO, O—HS, and N—HS hydrogen bonds into a three-dimensional supramolecular structure. Weak π–π interactions between the pyridine rings is also found [centroid–centroid distance = 3.8578 (14) Å].
S hydrogen bonds between the amino groups and the thiocyanate anions form an R42(8) motif. The complex molecules are linked by O—HO, O—HS, and N—HS hydrogen bonds into a three-dimensional supramolecular structure. Weak π–π interactions between the pyridine rings is also found [centroid–centroid distance = 3.8578 (14) Å].
