Tris(diisopropyl di­thio­phosphato-κ²S,S′)ruthenium(III)

In the title complex, [Ru(C₆H₁₄O₂PS₂)₃], the coordination environment of the Ru^III atom is distorted octa­hedral, defined by six S atoms from three S,S′-bidentate diisopropyl di­thio­phosphate ligands. The average Ru—S bond length is 2.41 (1) Å and the average S—Ru—S bite angle is 81.13 (19)°.

Tetra­ethyl­ammonium trichlorido(N,N′-di­methyl­formamide-κO)zinc

The title complex salt, (C₈H₂₀N)[ZnCl₃(C₃H₇NO)], contains one [Et₄N]⁺ cation (Et is ethyl) and one [ZnCl₃(DMF)]⁻ anion (DMF is di­methyl­formamide). In the anion, the zinc atom is tetra­hedrally coordinated by a DMF ligand via the O atom and by three terminal Cl atoms. The average Zn—Cl bond length and Cl—Zn—Cl angle are 2.243 (11) Å and 114 (3)°, respectively.