cis-Chloridobis(4,4′-dimethyl-2,2′-bipyridine-κ²N,N′)oxidovanadium(IV) chloride ethanol monosolvate monohydrate

In the title compound, [VClO(C₁₂H₁₂N₂)₂]Cl·C₂H₅OH·H₂O, the V^IV atom is six-coordinated in a distorted octa­hedral geometry by four N atoms from two 4,4′-dimethyl-2,2′-bipyridine ligands, one O atom and one Cl atom. In the crystal, O—H...Cl, C—H...O and C—H...Cl hydrogen bonds and π–π contacts between the pyridine rings [centroid–centroid distances = 3.7236 (17) and 3.6026 (19) Å] stabilize the structure. Intra­molecular C—H...O and C—H...Cl hydrogen bonds are also present.

Trichlorido(6-methyl-2,2′-bipyridine-κ²N,N′)(dimethyl­sulfoxide-κO)indium(III)

In the title compound, [In(C₁₁H₁₀N₂)Cl₃(C₂H₆OS)], the In^III cation is six-coordinated in a distorted octa­hedral configuration by two N atoms from the chelating 6-methyl-2,2′-bipyridine ligand, one O atom from a dimethyl­sulfoxide group and three Cl⁻ anions. Weak inter­molecular C—H...O and C—H...Cl hydrogen bonds and intra­molecular C—H...Cl hydrogen bonds are present in the structure.