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In the title compound, [CuI(C8H8N2S)(C18H15P)2]·CH3OH, the coordination environment around the CuI atom is distorted tetra­hedral, defined by two P atoms of two triphenyl­phosphane ligands, one S atom of a 5-methyl-1H-benzimidazole-2(3H)-thione ligand and one I atom. The complex mol­ecules and the methanol solvent mol­ecules are connected via N—H...O and O—H...I hydrogen bonds, forming a chain along [010]. An intra­molecular N—H...I hydrogen bond is also observed.
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