(N,N,N′,N′-Tetra­methyl­ethylenediamine-κN)bis­(2,4,6-trimethyl­phenolato-κO)germanium(II)

In the title compound, [Ge(C₉H₁₁O)₂(C₆H₁₆N₂)], the Ge^II atom is coordinated in a distorted trigonal–pyramidal geometry by two O atoms belonging to two 2,4,6-trimethyl­phenolate ligands and one N atom of a tetra­methyl­ethylenediamine ligand. Comparing the structure with published data of similar compounds shows that the Ge—O bonds are covalent and the Ge—N bond is coordinated.

Bis(μ-propan-2-olato-κ²O:O)bis­[chlor­ido(propan-2-ol-κO)bis­(pro­pan-1-ol­ato-κO)tin(IV)]

The binuclear centrosymmetric title compound, [Sn₂(C₃H₇O)₆Cl₂(C₃H₈O)₂], exhibits an edge-shared double octahedral exhibits an edge-shared octa­hedral structure, which is distorted owing to the presence of asymmetric intra­molecular hydrogen bonds between the axially coordinated isopropanol and isopropoxide ligands. The H atom of the hy­droxy group is located nearer to an isoprop­oxy group with the longest Sn—O bond [2.1789 (17) Å].