metal-organic compounds
Open access
In the title compound, (C6H20N4)2[Ge2S6], the dimeric [Ge2S6]4− anion is formed by two edge-sharing GeS4 tetrahedral units. The average terminal and bridging Ge—S bond lengths are 2.158 (14) and 2.276 (6) Å, respectively. The anions and the diprotonated ammonium cations are organized into a three-dimensional network by N—HS and N—HN hydrogen bonds.
metal-organic compounds
Open access
In the title compound, (C6H17N3)2[Ge2S6], the dimeric [Ge2S6]4− anion is formed by two edge-sharing GeS4 tetrahedral units. The average terminal and bridging Ge—S bond lengths are 2.164 (2) and 2.272 (8) Å, respectively. The dimeric inorganic anions and the organic piperazinium cations are organized into a three-dimensional network by N—HS hydrogen bonds.
metal-organic compounds
Open access
In the title compound, (C10H26N4)2[Ge2S6], the dimeric [Ge2S6]4− anion formed by two edge-sharing GeS4 tetrahedral units lies around an inversion centre. The average terminal and bridging Ge—S bond lengths are 2.162 (7) and 2.267 (15) Å, respectively. The inorganic anions and organic cations are organized into a three-dimensional network by numerous N—HS hydrogen bonds.