metal-organic compounds
Open access
In the title compound, [Ni(C9H6N3O2)2(H2O)4]·10H2O, the NiII ion lies on a twofold rotation axis and displays a slightly distorted octahedral geometry defined by two N atoms from two monodentate 4-(1,2,4-triazol-4-yl)benzoate ligands and four water molecules, two of which also lie on the twofold rotation axis. In the crystal, the complex molecules and uncoordinated water molecules are linked via intermolecular O—HN and O—HO hydrogen bonds, forming a three-dimensional supramolecular network. π–π interactions between the benzene rings provide additional stability of the crystal packing [centroid–centroid distance = 3.792 (2) Å].
organic compounds
Open access
In the title chalcone derivative, C20H22O6, the dihedral angle between the mean planes of the benzene rings is 15.77 (6)°. The H atoms of the central C=C double bond are in a trans configuration. There are a number of C—HO interactions and a C—Hπ interaction present in the crystal structure.