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Two distinct lead-free piezoceramics were investigated by X-ray, neutron and electron diffraction. The experiments revealed the coexistence of rhombohedral R3c and tetragonal P4bm phases.

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The origin of the electric field-induced strain in the polycrystalline ceramic 0.92Bi1/2Na1/2TiO3-0.06BaTiO3-0.02K1/2Na1/2NbO3 was investigated using in situ high-resolution X-ray and neutron diffraction techniques.
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