trans-Chlorido­(4-fluoro­benzene­thiol­ato-κS)bis­(tri­phenyl­phosphane-κP)palladium(II) methanol hemisolvate

The title compound, [Pd(SC₆H₄F-p)Cl(PPh₃)₂]·0.5CH₃OH, features a Pd^II complex with two tri­phenyl­phosphane (PPh₃) ligands arranged in a trans conformation, with one chloride and one 4-fluoro­benzene­thiol­ate ligand completing the coordination sphere, giving rise to a slightly distorted square-planar geometry of the Pd^II ion. The methanol solvent mol­ecule is disordered about an inversion centre with an occupancy of 0.25 for each molecule. In the crystal, weak C—H...Cl hydrogen-bonding inter­actions between the complex mol­ecules generate chain frameworks parallel to [010].

Di­chlorido­(4,4′-di-tert-butyl-2,2′-bi­pyridine-κ²N,N′)palladium(II) dimethyl sulfoxide monosolvate monohydrate

The title compound, [PdCl₂(C₁₈H₂₄N₂)]·(CH₃)₂SO·H₂O, the Pd^II ion is in a distorted square-planar geometry. The Pd—N bond distances are 2.022 (2) and 2.027 (2) Å, the Pd—Cl bond distances are 2.2880 (7) and 2.2833 (7) Å, and the ligand bite angle is 80.07 (9)°. The dimethyl sulfoxide and water mol­ecules form linear chains along [100] by O—H...O and O—H...S hydrogen bonds, generating eight- and 12-membered rings. C—H...Cl inter­actions link the chains, forming a three-dimensional arrangement. In addition, the 4,4-di-tert-butyl-2,2′-bi­pyridine ligand exhibits π–π stacking inter­actions [centroid–centroid distances = 3.8741 (15) and 3.8353 (15) Å]. The DMSO solvent is disordered and was refined with an occupancy ratio of 0.866 (3):0.134 (3).

(2,2′-Bi­pyridine-κ²N,N′)di­chloridopalladium(II) 1,4-dioxane hemisolvate

The asymmetric unit of the title compound, [PdCl₂(C₁₀H₈N₂)]·0.5C₄H₈O₂, consists of one Pd^II complex mol­ecule and a half-mol­ecule of 1,4-dioxane, the complete mol­ecule being generated by inversion symmetry. The Pd^II atom has an almost square-planar coordination formed by the 2,2′-bi­pyridine ligand and two chloride ligands. Two intra­molecular C—H...Cl hydrogen bonds occur. In the crystal, the Pd^II complex and 1,4-dioxane mol­ecules are connected by C—H...O hydrogen bonds, forming a layer parallel to (10-1). Within the layer, weak π–π inter­actions [centroid–centroid distance = 3.817 (4) Å] are observed between the pyridine rings.

Bis(2,3-di­chloro­phen­yl) di­sulfide

The title compound, C₁₂H₆Cl₄S₂, features an S—S bond [2.0252 (8) Å] that bridges two 2,3-di­chloro­phenyl rings with a C—S—S—C torsion angle of 88.35 (11)°. The benzene rings are normal one to the other with a dihedral angle of 89.83 (11)°. The crystal structure features inter­molecular Cl...Cl [3.4763 (11) Å] and π–π stacking inter­actions [centroid–centroid distances = 3.696 (1) and 3.641 (2) Å]. Intra­molecular C—H...S inter­actions are also observed.

(tert-But­yl)(2-hy­droxy­eth­yl)ammonium chloride

In the cation of the title mol­ecular salt, C₆H₁₆NO⁺·Cl⁻, the N—C—C—O torsion angle is 176.5 (2)°. In the crystal, the cations and chloride ions are linked by N—H...O and O—H...O hydrogen bonds, generating a two-dimensional network parallel to (100).