trans-Chlorido­(4-fluoro­benzene­thiol­ato-κS)bis­(tri­phenyl­phosphane-κP)palladium(II) methanol hemisolvate

The title compound, [Pd(SC₆H₄F-p)Cl(PPh₃)₂]·0.5CH₃OH, features a Pd^II complex with two tri­phenyl­phosphane (PPh₃) ligands arranged in a trans conformation, with one chloride and one 4-fluoro­benzene­thiol­ate ligand completing the coordination sphere, giving rise to a slightly distorted square-planar geometry of the Pd^II ion. The methanol solvent mol­ecule is disordered about an inversion centre with an occupancy of 0.25 for each molecule. In the crystal, weak C—H...Cl hydrogen-bonding inter­actions between the complex mol­ecules generate chain frameworks parallel to [010].

Bis(2,3-di­chloro­phen­yl) di­sulfide

The title compound, C₁₂H₆Cl₄S₂, features an S—S bond [2.0252 (8) Å] that bridges two 2,3-di­chloro­phenyl rings with a C—S—S—C torsion angle of 88.35 (11)°. The benzene rings are normal one to the other with a dihedral angle of 89.83 (11)°. The crystal structure features inter­molecular Cl...Cl [3.4763 (11) Å] and π–π stacking inter­actions [centroid–centroid distances = 3.696 (1) and 3.641 (2) Å]. Intra­molecular C—H...S inter­actions are also observed.